سنتز نانوذرات کلسیم اکسید از ضایعات استخوان ماهی‌مرکب سواحل خلیج‌فارس و بررسی خصوصیات ترمولومینسانس آن در پرتوهای گاما

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه فیزیک، دانشکده علوم و فناوری نانو و زیستی، دانشگاه خلیج فارس، بوشهر، ایران

2 نیروگاه اتمی بوشهر، معاونت ایمنی، بوشهر، ایران

3 گروه مهندسی شیمی، دانشکده نفت، گاز و پتروشیمی، دانشگاه خلیج فارس، بوشهر، ایران

4 دانشکده مهندسی، دانشگاه خلیج فارس، بوشهر، ایران.

چکیده

در این پژوهش ضایعات استخوان ماهی‌مرکب از سواحل خلیج‌فارس جمع‌آوری شده است و پس از شستشو و خالص‌سازی، نانو-ذرات کربنات‌کلسیم خالص توسط فرآیند آسیاب مکانیکی و سپس نانوذرات کلسیم اکسید از کلسینه کردن نانوذرات کربنات کلسیم در کوره سنتز شده است. ساختار و شکل و اندازه نانوذرات بدست آمده به‌وسیله الگوی پراش پرتوایکس و میکروسکوپ الکترونی روبشی مورد بررسی قرار گرفته‌اند و با استفاده از روش ویلیامسون-هال اندازه تقریبی 68 نانومتر برای نانوبلورک‌ها به‌دست آمده که با تصاویر میکروسکوپ الکترونی روبشی هم‌خوانی دارد. نانوذرات به‌وسیله تابش‌های متفاوت از پرتو گاما به‌وسیله چشمه 60Co مورد تابش قرار گرفته‌اند و رفتار ترمولومینسانس آن‌ها در برابر پرتوهای گاما مورد بررسی قرار گرفته است. نتایج به‌دست آمده نشان می‌دهد که نانوذرات در دزهای بالا نسبت به پرتوهای گاما از خود حساسیت نشان می‌دهند و در یک بازه KGy 1 تا 5 KGy رفتار خطی دارند. نمودار محو شدگی نمونه‌ها در یک بازه 30 روزه کاهش 12 درصدی را از خود نشان داده‌اند.

کلیدواژه‌ها

عنوان مقاله [English]

Synthesis of calcium oxide nanoparticles from squid bone wastes of Persian Gulf coasts and investigating Its thermoluminescence properties in gamma rays

نویسندگان [English]

  • Mohsen Mehrabi 1
  • Sonia Karami 1
  • Kosar Kohzadi 1
  • Hossein Parvaz 2
  • Farzad Bayat Mastalinezhad 3
  • Fariba Havaei 4
1 Physics Department, Persian Gulf University, Bushehr 7516913718, Iran
2 Bushehr Nuclear Power Plant, Safety Deputy, Bushehr, Iran
3 Faculty of Petroleum, Gas and Petrochemical Engineering, Persian Gulf University, Bushehr, Iran
4 Faculty of Engineering, Persian Gulf University, Bushehr, Iran
چکیده [English]

In this research, Squid bone wastes were collected from the coast of the Persian Gulf. After washing and purification, pure calcium carbonate nanoparticles and calcium oxide nanoparticles were synthesized by mechanical grinding and calcination. The structure, shape, and size of the nanoparticles have been investigated by X-ray diffraction pattern and scanning electron microscope, and using the Williamson-Hall method, an approximate size of 68 nm has been obtained for them, which is consistent with the scanning electron microscope images. Gamma rays irradiated to nanoparticles from a 60Co source and their thermoluminescence properties were investigated. The obtained results illustrate that nanoparticles show sensitivity to gamma rays in high doses and have a linear behavior in a range of 1 kg Gy to 5 kg Gy. The fading curve of the samples showed a 12% decrease in 30 days.

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