Investigation of the structural properties and thermoluminescence of Zn₂SiO₄/SiO₂ nanoparticles doped with Manganese impurity under Gamma ray irradiation

Document Type : Original Article

Authors

1 Faculty of Physics, University of Kashan, Kashan, Iran

2 Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran

Abstract

The present article reports thermoluminescence studies of Zn₂SiO₄/SiO₂ nanoparticles doped with manganese impurity. The sample was prepared using the sonochemical method, one of the methods for producing nanoparticles. The structural and morphological characteristics of the fabricated nanoparticles were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). Additionally, the thermoluminescence (TL) glow curve for the nanoparticles irradiated with gamma rays was investigated and exhibited three distinct TL glow peaks at temperatures of 170℃, 257℃, and 338℃. Among the doped nanoparticles, the sample doped with manganese ions at a concentration of 0.08 mol% showed the highest thermoluminescence intensity. The analysis results indicated that the fabricated nanoparticles have significant sensitivity to gamma radiation.

Keywords

References

  1. C. Aparna, P. K. Shetty, M. Mahesha. Structural optimization of indium oxide thin film for gamma dosimetry applications. Mat. Sci. Semiconductor Processing 150 (2022) 106931.
  2. F. Flakus. Detecting and measuring ionizing radiation- A short history. IAEA Bulletin 23 (4) (1982) 31-36.
  3. A. Vidya Saraswathi, N. S. Prabhu, K. Naregundi, M. I. Sayyed, M. S. Murari, A. H. Almuqrin, S. D. Kamath. Thermoluminescence investigations of Ca2Al2SiO7: Dy3+ phosphor for gamma dosimetry applications. Mat. Chem. Phys. 281 (2022) 125872.
  4. B. Chandra, R. K. Chandrakar, V. Chandra, R. Baghel. Effect of particle size on activation energy and peak temperature of the thermoluminescence glow curve of undoped ZnS nanoparticles. Luminescence 31 (2) (2016) 478-486.
  5. R. Chen, S. W. S. McKeever. Characterization of nonlinearities in the dose dependence of thermoluminescence. Radiat. Measurements. 23 (4) (1994) 667-673.
  6. K. K. Gupta, N. S. Dhoble, D. K. Burghate, S. J. Dhoble. Luminescence properties of nanocrystalline Mg2P2O7: Eu phosphor. Luminescence 33 (5) (2018) 947-953.
  7. M. Zahedifar, F. Almasifard, E. Sadeghi, M. K. Biroon, A. Ramazani-Moghaddam-Arani. Thermoluminescence kinetic analysis and dosimetry features of MgSO4: Dy and MgSO4: Cu nano-rods. Radiat. Phys. Chem. 125 (2016) 127-133.
  8. E. Habibi, M. Zahedifar, E. Sadeghi. Synthesis and thermoluminescence analysis of LiBaF3: M (M= Cu, Ce, Er) nanoparticles. J. Luminescence 237 (2021) p. 118173.
  9. M. Bagheri, E. Sadeghi, M. Zahedifar, S. Harooni. Thermoluminescence properties of Cu doped α-Al2O3 crystals synthesized by a solid state method. Radiat. Phys. Chem. 209 (2023) 110971.
  10. M. Talebi, E. Sadeghi, M. Zahedifar, S. Harooni, Synthesis, structural characteristics and thermoluminscence features of KCl: Mn and KCl: Ce phosphors. Nucl. Instrum. Methods Phys. Res. Sec. B: Beam Interact. Mater. Atoms 530 (2022). 29-38.
  11. S. Sharma, N. Brahme, D. P. Bisen, P. Dewangan, S. Tigga, G. Tiwari, Ayush Khare. Study on photoluminescence and thermoluminescence properties of UV-irradiated CaSrAl2 SiO 7: Ce 3+ phosphors. J. Mater. Sci: Mater. Electron 29 (2018) 1412-1419.
  12. S. Miao, Z. Xia, M. S. Molokeev, J. Zhang, Q. Liu. Crystal structure refinement and luminescence properties of blue-green-emitting CaSrAl2SiO7: Ce3+, Li+, Eu 2+ phosphors. J. Mater. Chem. C. 3 (32) (2015) 8322-8328.
  13. K.-S. Sohn, B. Cho, H. D. Park. Excitation energy-dependent photoluminescence behavior in Zn2SiO4: Mn phosphors. Mater. Letters 41 (6) (1999) 303-308.
  14. R. Selomulya, S. Ski, K. Pita, C. Kam, Q. Zhang, and S. Buddhudu. Luminescence properties of Zn2SiO4: Mn2+ thin-films by a sol–gel process. Mater. Sci. Eng.: B. 100 (2) (2003) 136-141.
  15. N. Taghavinia, G. Lerondel, H. Makino, A. Yamamoto, T. Yao, Y. Kawazoe, T. Goto. Growth of luminescent Zn2SiO4: Mn2+ particles inside oxidized porous silicon: emergence of yellow luminescence. J. Crystal Growth 237 (2002) 869-873.
  16. M. Naderi, E. Sadeghi, M. Zahedifar. Fabrication and investigation of thermoluminescence properties of Zn2SiO4/SiO2 nanophosphor with manganese impurity. Radiat. Phys. Chem. 225 (2024) 112126.
  17. J. B. Yoo, H. J. Yang, N. H. Hur. Controlled synthesis of luminescent Mn-doped Zn2SiO4 microspheres by thermal hydrolysis of urea. J. Luminescence 243 (2022) 118608.
  18. A. Stochioiu, F. Scarlata, I. Georgescuc, and F. Alexiud. Method to manufacture the thermoluminescent detector chips using LiF crystal. J. Optoelectronics Adv. Mater. 6 (4) (2004) 1357-1363, 2004.
  19. H. Silva. The effect of grain size and teflon matrix on the energy dependence of thermoluminescent dosimeters. Int. J. Radiat. Appl. Instrum. Part A. Appl. Radiat. Isot. 40 (2) (1989) 109-116.
  20. S. Shinde, A. Lakshmanan, B. Bhatt, R. Bhatt. Photo transfer thermoluminescence in CASO4: Dy—grain size dependence. Nucl. Instrum. Methods Phys. Res. Sec. B: Beam Interact. Mater. Atoms 31 (4) (1988) 592-596.
  21. S. Armitage, R. Bailey.The measured dependence of laboratory beta dose rates on sample grain size. Radiat. Measurements 39 (2) (2005) 123-127.
  22. M. Bagheri, E. Sadeghi, M. Zahedifar. Fabrication and investigation of thermoluminescence properties of gamma irradiated Dy-doped crystalline alumina," Nucl. Instrum. Methods Phys. Res. Sec. B: Beam Interact. Mater. Atoms 537 (2023) 46-53.
  23. J. Srivastava, S. Supe. Thermoluminescence processes in CaSO4: Dy. Dependence on stopping power. J. Phys. D: Appl. Phys. 13 (12) (1980) 2337.

Files

Share

How to cite

Statistics