Distribution coefficient determination of cobalt on alluvium soil of Anarak Nuclear Repository

Document Type : Original Article

Authors

1 Iran radioactive waste company, Atomic energy organization, Tehran, Iran

2 Radiation Application Research School, Nuclear science and technology Research Institute, Tehran, Iran

3 Nuclear fuel cycle Research School, Nuclear science and technology Research Institute, Tehran, Iran

Abstract

The safety assessment of Anarak site as the only center for the disposal of radioactive waste is of particular importance in order to maintain human health and the environment. Distribution coefficients of radioactive materials in the soils of the area under study is one of the influential parameters in the safety assessment calculations. Therefore, in this study, the distribution coefficient of cobalt in the alluvial soil of Anarak waste was determined by the batch method and two parameters of concentration and soil to solution ratio were studied. Linear adsorption isotherms, Friendlich and Langmuir were also analyzed to determine the adsorption behavior of cobalt in Anarak soil. The average value of cobalt distribution coefficient in the mentioned soil was calculated equal to 247.18 mL / g. The adsorption behavior of cobalt in Anarak soil followed the Langmuir adsorption isotherm with a positive and significant correlation. The maximum amount of cobalt uptake was determined as 0.029 mg / g soil. The results of the distribution coefficient obtained in this study are lower than the most of the values ​​presented in the other previous researches, which can be related to the soil texture (sandy loam) and the other soil characteristics.
 

Keywords


1. Environmental Protection Agency, Understanding Variation in Partitioning Coefficients, Kd Values: VolumeI: The Kd Model, Methods Of Measurement, And, Application Of chemical Reaction Codes. Washington : Office Of Air and Radiation, 1999.
2. International Atomic Energy Agency, Safety Assessment Methodologies for Near Surface Disposal Facilities, Results of a co-ordinated research project. IAEA, Austria, 2004.
3. Environmental Protection Agency, Site Characterization for Subsurface Remediation. EPA/625/4-91/026, Office of Research and Development, U.S. Environmental Protection Agency, Cincinnati, Ohio, 1991.
4. ASTM (American Society of Testing and Materials). (1987). “24-hour Batch-Type Measurement of Contaminant Sorption by Soils and Sediments.” In Annual Book of ASTM Standards, Water and Environmental Technology, Volume 11.04, Philadelphia, Pennsylvania, pp. 163-167.
5. S. Sheppard, J. Long, B. Sanipelli, G. Sohlenius. Solid/liquid partition coefficients (Kd) for selected soils and sediments at Forsmark and Laxemar-Simpevarp. ECOMatters Inc. Canada (2009).
6. H. Vandenhove, C. Gil-García, A. Rigol, M.Vidal, New best estimates for radionuclide solid-liquid distribution coefficients in soils. Part 2: naturally occurring radionuclides. J. Environ. Radioact.100 (9) (2009) 697-703.
7. International Atomic Energy Agency, Derivation of activity limits for the disposal of radioactive waste in near surface disposal facilities, IAEA-TECDOC-1380. IAEA, Austria (2003).
8. L. Leyssens, B. Vinck, C. Van Der Straeten, F. Wuyts, L. Maes, Cobalt toxicity in humans-A review of the potential sources and systemic health effects. Toxicology. 15 (2017) 43-56.
9. B. Buchter, B. Davidoff, M. C. Amacher, C. Hinz, I. K. Iskandar, H. M. Selim, Correlation of Freundlich Kd and n retention parameters with soils and elements. Soil. Sci. 148 (1989) 370-379.
10. D. H. Thibault, M. I. Sheppard, P. A. Smith, A critical compilation and review of default soil solid/liquid partition coefficients, Kd, for use in environmental assessments. Atomic Energy of Canada Limited, AECL-10125. Canada,
1990.
11. M. A. Bangash, J. Hanif, M.Ali Khan, Sorption behavior of cobalt on illitic soil. Waste management, 12 (1992) 29-38.
12. International Atomic Energy Agency, Handbook of Parameter Values for the Prediction of Radionuclide Transfer in
Temperate Environments, Technical Report Series No. 364, IAEA, Austria, 1994.
13. C. Yu, User’s Manual for RESRAD Version 6. U.S. Department of Energy, Office of Scientific and Technical Information, 2001.
14. Environmental Agency of the State of Sao Paulo, Report establishment of guiding values for soils and groundwater
of the State of Sao Paulo. São Paulo, Brazil, 2001.
15. M. R. Soares, Distribution coefficient (Kd) of heavy metals in soils of the State of São Paulo. University of São Paulo.
(In Portuguese), 2004.
16. C. Gil-García, K. Tagami, S. Uchida, A. Rigol, M. Vidal, New best estimates for radionuclide solid-liquid distribution coefficients in soils. Part 3: miscellany of radionuclides (Cd, Co, Ni, Zn, I, Se, Sb, Pu, Am, and others). J. Environ.
Radioact. 100 (9) (2009) 704-715.
17. K. G.Varshney, S. Agrawal, K. Varshney, U. Sharma, S. Rani, Radiation stability of some thermally stable inorganic ion exchangers. J. Radioanal. Nucl. Chem. 82 (1984) 299-308.
18. V. K. Jain, R. A. Pandya, S. G. Pillai, Y. K. Agrawal, P. H. Kanaiya, Solid-phase extractive preconcentration and separation of lanthanum (III) and cerium (III) using a polymer-supported chelating calix [4] arene resin. J. Anal. Chem. 62 (2007) 104-112.
19. A. M. de Souza Braz, A. R. Fernandes, J. R. Ferreira, L. R. Alleoni. Distribution coefficients of potentially toxic elements in soils from the eastern Amazon. Environ. Sci. Pollut. Res. Int. 20 (10) (2013) 7231-742.
20. A. Taherian, A. Maleki, S. Zolghadri, H. Yousefnia, Z. Shiri-Yekta, S. Sarfi, H. Aghayan, S. Momenzadeh, Distribution coefficient determination of thorium on alluvium soil of Anarak Nuclear Repository. JonSat. 43 (1) (2022) 106-115